The Prince of Wales and Duchess of Cornwall were the last royals to visit Pakistan, as they visited areas devastated by quake and the capital Islamabad in 2006.
It said the royal couple would "visit programmes which empower young people... and also cover how communities in Pakistan are rapidly responding and adapting to the effects of climate change".
The Duchess of Cambridge's arrival look resembled an outfit Princess Diana wore during her time in Pakistan in 1996.
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Earlier this year, Jemima, 45, attended the wedding of Lady Gabriella Windsor, where William was also a guest.
The royal visit comes amid heightened tensions between Pakistan and India over the disputed region of Kashmir.
It was seen by many royal observers as a respectful nod to the traditions of the strict Muslim country.
Excitement built up on Monday, with '#RoyalVisitPakistan' trending on Twitter and television stations airing footage from historic royal visits, including one by Prince William's grandmother Queen Elizabeth in 1961.
All details of their engagements will be released by the palace on the day due to security considerations.
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When the Prince of Wales and the Duchess of Cornwall visited in 2006, they were forced to pull out of a visit to Peshawar in the North-West Frontier Province due to fears over their safety.
The Foreign Office also states on its website that "terrorists are very likely to try and carry out attacks in Pakistan".
Her visits saw her lay a wreath at Commonwealth war graves, tour Lahore's iconic Badshahi Mosque, and visit a centre for disabled Afghan refugees.
With Brexit looming, it comes as London hopes to bolster its global relationships, while Islamabad is keen to promote itself as a tourist destination amid concerns over security and violence in the region.
The High Commissioner said that the couple hopes to meet as many Pakistanis as possible, particularly the youth who are shaping the future of the country. We previously saw the duchess wearing Zeen earrings at a preview event for the tour in London at the Aga Khan Centre on October 2.
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Yusra Askari, a spokesman for industry body Fashion Pakistan, said: "The Duchess of Cambridge is a global fashion icon and trend setter".