For leader DeChambeau Hilton Head has proved a happy hunting ground in the past, the former US Amateur champion finishing fourth at the venue in his professional debut in 2016.
Ian Poulter moved one shot off the lead at the RBC Heritage after shooting a seven-under-par 64 in the second round.
World number one Dustin Johnson, fresh off a 10th-place finish at the Masters on Sunday, was six shots off the pace after mixing three birdies with a bogey for a two-under 69 and 138 total.
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DULUTH, Ga. (AP) - Jay Haas almost shot his age while taking a one-stroke lead over Steve Flesch in the opening round of the PGA Tour Champions' Mitsubishi Electric Classic in Georgia. He's had three top 10s this season, including a second last month at the Arnold Palmer Invitational. Poulter has now shot five sub-70 rounds in his last six appearances around Harbour Town. "You have to be on your game", Poulter said.
"My form has been pretty consistent", Poulter said. 'I can free myself up in my mind.
It was made all the more impressive by the fact that Poulter did not even play a practice round at the Harbour Town course.
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Kim began on the back nine and birdied 13 from 18 feet, then suffered a triple-bogey at the par-3 14th. 'But I'm having great feel around the greens and I feel really confident'.
Three more gains against a lone bogey on the inward journey have him in good position ahead of the weekend following his T5 result at Augusta National last week.
Much of the field thrived in mild, sunny conditions where even the course's typically hard closing stretch of No. 16, No. 17 and No. 18 along windy Calibogue Sound played much tamer than a typical round. Michael Kim went from an opening 76 to 66 in the second round.
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Among those missing the cut were Paul Casey, Marc Leishman and Tyrell Hatton, all ranked among the top 20.